🔗 LK-99

🔗 Korea 🔗 Physics 🔗 Chemicals 🔗 Electrical engineering 🔗 Materials

LK-99 is a proposed ambient pressure and room-temperature superconductor with a gray‒black appearance.^: 8 LK-99 has a hexagonal structure slightly modified from lead‒apatite and is claimed to function as a superconductor below 400 K (127 °C; 260 °F).^: 1 The material was investigated by a team of Sukbae Lee et al. from the Korea Institute of Science and Technology (KIST).^: 1 As of 26 July 2023 the discovery of LK-99 has not been peer reviewed or independently replicated.

The chemical composition of LK-99 is approximately Pb₉Cu(PO₄)₆O such that—compared to pure lead-apatite (Pb₁₀(PO₄)₆O)^: 5—approximately one quarter of Pb(2) ions are replaced by Cu(II) ions.^: 9 This partial replacement of Pb²⁺ ions (measuring 133 picometre) with Cu²⁺ ions (measuring 87 picometre) is said to cause a 0.48% reduction in volume, creating internal stress inside the material.^: 8

The internal stress is claimed to cause a heterojunction quantum well between the Pb(1) and oxygen within the phosphate ([PO₄]³⁻) generating a superconducting quantum well (SQW).^: 10 Lee et al claim to show LK-99 exhibits a response to a magnetic field (Meissner effect) when chemical vapor deposition is used to apply LK-99 to a non-magnetic copper sample.^: 4 Pure lead-apatite is an insulator, but Lee et al claim copper-doped lead-apatite forming LK-99 is a superconductor, or at higher temperatures, a metal.^: 5