🔗 Relativistic Quantum Chemistry

🔗 Physics 🔗 Physics/relativity 🔗 Chemistry

Relativistic quantum chemistry combines relativistic mechanics with quantum chemistry to explain elemental properties and structure, especially for the heavier elements of the periodic table. A prominent example of such an explanation is the color of gold: due to relativistic effects, it is not silvery like most other metals.

The term relativistic effects was developed in light of the history of quantum mechanics. Initially quantum mechanics was developed without considering the theory of relativity. Relativistic effects are those discrepancies between values calculated by models that consider and that do not consider relativity. Relativistic effects are important for the heavier elements with high atomic numbers. In the most common layout of the periodic table, these elements are shown in the lower area. Examples are the lanthanides and actinides.

Relativistic effects in chemistry can be considered to be perturbations, or small corrections, to the non-relativistic theory of chemistry, which is developed from the solutions of the Schrödinger equation. These corrections affect the electrons differently depending on the electron speed relative to the speed of light. Relativistic effects are more prominent in heavy elements because only in these elements do electrons attain sufficient speeds for the elements to have properties that differ from what non-relativistic chemistry predicts.